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Mini Review: Some Peculiarities of Chemical Mesoscopics and This Scientific Trend Development Perspective

Received: 5 July 2021     Accepted: 19 July 2021     Published: 26 August 2021
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Abstract

In present mini review the definition of new scientific trend “chemical mesoscopics”, which is based on the ideas of the mesoscopic physics (mesoscopics) and also more latest mesoscopic chemistry, is given. This new scientific trend includes quantum notions on mesoparticle reactivity in chemical reactions. In these cases the negative charges quants interactions (interference) are considered as well as the interactions of negative and positive charges (annihilation). The schemes of the chemical bonds formation at the reactions flowing into mesoscopic reactors are presented. The especial attention is devoted to the interactions of metal (Copper, Nickel) carbon mesoparticles with such oxidizers as Ammonium Polyphosphate and Aluminum Oxide. In these reactions it is observed the reduction of Phosphorus and Aluminum, the growth of mesocomposite metal atomic magnetic moment and the simultaneous increasing of spin quantity on the mesocomposite carbon shell. The introduction of “annihilation” notion explains the increasing of magnetic characteristics. The modification of polymeric materials (on example of epoxy resins) by metal carbon mesocomposites is considered. For the mesoparticle (nanostructures) reactivity estimation the proposals are done. These proposals are concluded in the using of Fractal Theory ideas (Kolmogorov – Avrami equations) together with energetic analogs of reactivity theory.

Published in Science Journal of Chemistry (Volume 9, Issue 4)
DOI 10.11648/j.sjc.20210904.12
Page(s) 97-104
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Chemical Reactions, Charge Quantization, Interference, Annihilation, Nanostructures Reactivity, Red Ox Reactions, Atomic Magnetic Moments, Kolmogorov-Avrami Equations Changed

References
[1] Kodolov V. I., Trineeva V. V. New scientific trend – Chemical Mesoscopics – Chemical Physics & Mesoscopics, 2017. V. 19. N 3. Pp. 454 – 465.
[2] Kodolov V. I., Kodolova-Chukhontzeva V. V., Terebova N. S., Shabanova I. N. The explanation of magnetic metal carbon mesocomposites synthesis peculiarities by means of mesoscopic notions. – Academ. J. Polym. Sci. 2019, 3 (2): 555613.
[3] Moskaletz M. V. Fundamentals of Mesoscopic Physics. – Khar’kov: NTU KhPI, 2010 – 180p.
[4] Ruedenberg K. Physical Nature of Chemical Bond. – M.: Publ “Mir”, 1964 – 162p.
[5] Kodolov V. I., Kodolova-Chukhotzeva V. V., Shabanova I. N. et al. Review: Possible Fields of metal carbon mesocomposites application. – In Book: Innovation and Challenges in Modern Physical Chemistry. Research and Practice. – N. Y.: Nova Sciences Publishers, Inc., 2020, 195p. – Pp. 57–122.
[6] Kodolov V. I., Trineeva V. V., Pershin Yu. V. et al. Method of metal carbon nanocomposites obtaining from metal oxides and polyvinyl alcohol. –Pat. RU 2018122 001, 2020.
[7] Kodolov V. I., Kodolova –Chukhontseva V. V. Fundamentals of Chemical Mesoscopics. – Monograph. - Izhevsk: Publisher – M. T. Kalashnikov Izhevsk State Technical University, 2019 – 218p.
[8] Mustakimov R. V., Kodolov V. I., Shabanova I. N., Terebova N. S. Modification of copper carbon nanocomposites with the using of Ammonium Polyphosphate for the application as modifiers of epoxy resins.// Chemical Physics & Mesoscopics, 2017. V. 19. N 1. Pp. 50–57.
[9] Kodolov V. I., Trineeva V. V., Kopylova A. A et al. Mechanochemical modification of metal carbon nanocomposites. // Chemical Physics & Mesoscopics, 2017. V. 19. N 4. Pp. 569–580.
[10] Kodolov V. I., Trineeva V. V., Terebova N. S. et al. The change of electron structure and magnetic characteristics of modified copper carbon nanocomposites.// Chemical Physics & Mesoscopics, 2018. V. 20. N 1. Pp. 72–79.
[11] Shabanova I. N., Kodolov V. I., Terebova N. S., Trineeva V. V. (2012) X ray electro spectroscopy in investigation of metal/carbon nanosystems and nanostructured materials. (P. 252) Izhevsk–Moscow: Publ. “Udmurt University”.
[12] Shabanova I. N., Terebova N. S. Kodolov V. I. et al. (2013) The investigation of metal or carbon nanocomposites electron structure by X ray photoelectron spectroscopy. in Book: Nanostructure, nanosystems and nanostructured materials. Theory, production and development (Pp. 177–230). Toronto, Canada – New Jersey, USA: Apple Academic Press.
[13] Kodolov V. I., Lipanov A. M., Trineeva V. V. et al. (2013) The changes of properties of materials modified by metal/carbon nanocomposites. Ibid. (Pp. 327 – 373).
[14] Kodolov V. I., Trineeva V. V. (2013) Theory of modification of polymeric materials by super small quantities of metal/carbon nanocomposites.// Chemical Physics & Mesoscopy, V. 15. N 3. Pp. 351 – 363.
[15] Kodolov V. I., Trineeva V. V. (2012). Perspectives of idea development about nanosystems self organization in polymeric matrixes In book “The problems of nanochemistry for the creation of new materials” - Torun, Poland: IEPMD. (Pp. 75-100).
[16] Akhmetshina L. F., Lebedeva G. A., Kodolov V. I. (2012). Phosphorus containing metal/carbon nanocomposites and their application for the modification of intumescent fireproof coatings. // Journal of Characterization and Development of Novel Materials, 2012. V. 4. N 4. Pp. 451–468.
[17] Kodolov V. I., Kovyazina О. А., Trineeva V. V., Vasilchenko Yu. M., Vakhrushina М. А., Chmutin I. A. On the production of metal/carbon nanocomposites, water and organic suspensions on their basis.// VII International Scientific-Technical Conference “Nanotechnologies to the production – 2010”./ Proceedings. Fryazino, 2010. Pp. 52-53.
[18] Chashkin M. A. Kodolov V. I., Trineeva V. V. Metal/Carbon nanocomposites– Epoxy compositions Quantum Chemical Investigation and Experimental Modeling. // Polymers Research Journal, 2011. V. 5. N 1. Pp. 5 – 19.
[19] Patent 2337062 Russia Technique of obtaining carbon nanostructures from organic compounds and metal containing substances / Kodolov V. I., Kodolova V. V. (Trineeva), Semakina N. V., Yakovlev G. I., Volkova E. G. et al; declared on 28.08.2006, published on 27.10.2008.
[20] Kodolov V. I., Trineeva V. V., Kovyazina O. A., Vasilchenko Yu. M. Production and application of metal/carbon nanocomposites.// In book “The problems of nanochemistry for the creation of new materials” – Torun, Poland: IEPMD, 2012. Pp. 23 – 36.
[21] Akhmetshina L. F., Kodolov V. I., Tereshkin I. P., Korotin A. I. The influence of carbon metal containing nanostructures on strength properties of concrete composites. // Internet Journal “Nanotechnologies in Construction”, 2010. N 6. Pp. 35–46.
[22] Pershin Yu. V., Kodolov V. I. Polycarbonate modified with Cu-C nanocomposite.//in Book “The problems of nanochemistry for the creation of new materials” – Poland – Torun: Publ. IEPMD, 2012. – 250p. – Pp. 173 – 179.
[23] V. A. Pal’m. The introduction in theoretical organic chemistry. – M.: Publ. “High School”, 1974 – 446p.
[24] V. I. Kodolov. Possibilities of modeling in organic chemistry.// Organic Reactivity, 1965. V. 2. Iss. 4 (6). Pp. 11–17.
[25] V. I. Kodolov, S. S. Spasskiy. Parameters in Alfrey-Price and Taft equations. //Vysokomol. Soed., 1976. V. 18A. N 9. Pp. 1986–1992.
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    Kodolov Vladimir Ivanovitch, Kodolova-Chukhontzeva Vera Vladimirovna, Mustakimov Rostislav Valer’evitch. (2021). Mini Review: Some Peculiarities of Chemical Mesoscopics and This Scientific Trend Development Perspective. Science Journal of Chemistry, 9(4), 97-104. https://doi.org/10.11648/j.sjc.20210904.12

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    ACS Style

    Kodolov Vladimir Ivanovitch; Kodolova-Chukhontzeva Vera Vladimirovna; Mustakimov Rostislav Valer’evitch. Mini Review: Some Peculiarities of Chemical Mesoscopics and This Scientific Trend Development Perspective. Sci. J. Chem. 2021, 9(4), 97-104. doi: 10.11648/j.sjc.20210904.12

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    AMA Style

    Kodolov Vladimir Ivanovitch, Kodolova-Chukhontzeva Vera Vladimirovna, Mustakimov Rostislav Valer’evitch. Mini Review: Some Peculiarities of Chemical Mesoscopics and This Scientific Trend Development Perspective. Sci J Chem. 2021;9(4):97-104. doi: 10.11648/j.sjc.20210904.12

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  • @article{10.11648/j.sjc.20210904.12,
      author = {Kodolov Vladimir Ivanovitch and Kodolova-Chukhontzeva Vera Vladimirovna and Mustakimov Rostislav Valer’evitch},
      title = {Mini Review: Some Peculiarities of Chemical Mesoscopics and This Scientific Trend Development Perspective},
      journal = {Science Journal of Chemistry},
      volume = {9},
      number = {4},
      pages = {97-104},
      doi = {10.11648/j.sjc.20210904.12},
      url = {https://doi.org/10.11648/j.sjc.20210904.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20210904.12},
      abstract = {In present mini review the definition of new scientific trend “chemical mesoscopics”, which is based on the ideas of the mesoscopic physics (mesoscopics) and also more latest mesoscopic chemistry, is given. This new scientific trend includes quantum notions on mesoparticle reactivity in chemical reactions. In these cases the negative charges quants interactions (interference) are considered as well as the interactions of negative and positive charges (annihilation). The schemes of the chemical bonds formation at the reactions flowing into mesoscopic reactors are presented. The especial attention is devoted to the interactions of metal (Copper, Nickel) carbon mesoparticles with such oxidizers as Ammonium Polyphosphate and Aluminum Oxide. In these reactions it is observed the reduction of Phosphorus and Aluminum, the growth of mesocomposite metal atomic magnetic moment and the simultaneous increasing of spin quantity on the mesocomposite carbon shell. The introduction of “annihilation” notion explains the increasing of magnetic characteristics. The modification of polymeric materials (on example of epoxy resins) by metal carbon mesocomposites is considered. For the mesoparticle (nanostructures) reactivity estimation the proposals are done. These proposals are concluded in the using of Fractal Theory ideas (Kolmogorov – Avrami equations) together with energetic analogs of reactivity theory.},
     year = {2021}
    }
    

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    AU  - Kodolov Vladimir Ivanovitch
    AU  - Kodolova-Chukhontzeva Vera Vladimirovna
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    AB  - In present mini review the definition of new scientific trend “chemical mesoscopics”, which is based on the ideas of the mesoscopic physics (mesoscopics) and also more latest mesoscopic chemistry, is given. This new scientific trend includes quantum notions on mesoparticle reactivity in chemical reactions. In these cases the negative charges quants interactions (interference) are considered as well as the interactions of negative and positive charges (annihilation). The schemes of the chemical bonds formation at the reactions flowing into mesoscopic reactors are presented. The especial attention is devoted to the interactions of metal (Copper, Nickel) carbon mesoparticles with such oxidizers as Ammonium Polyphosphate and Aluminum Oxide. In these reactions it is observed the reduction of Phosphorus and Aluminum, the growth of mesocomposite metal atomic magnetic moment and the simultaneous increasing of spin quantity on the mesocomposite carbon shell. The introduction of “annihilation” notion explains the increasing of magnetic characteristics. The modification of polymeric materials (on example of epoxy resins) by metal carbon mesocomposites is considered. For the mesoparticle (nanostructures) reactivity estimation the proposals are done. These proposals are concluded in the using of Fractal Theory ideas (Kolmogorov – Avrami equations) together with energetic analogs of reactivity theory.
    VL  - 9
    IS  - 4
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Author Information
  • Mesocomposites Department, High-Educational Centre of Chemical Physics & Mesoscopics, Udmurt Federal Research Centre, Russian Academy of Sciences, Izhevsk, Russia

  • Mesocomposites Department, High-Educational Centre of Chemical Physics & Mesoscopics, Udmurt Federal Research Centre, Russian Academy of Sciences, Izhevsk, Russia

  • Mesocomposites Department, High-Educational Centre of Chemical Physics & Mesoscopics, Udmurt Federal Research Centre, Russian Academy of Sciences, Izhevsk, Russia

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